Browsing by Author Laetitia Rapenne

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  • Authors: Abderrahime Sekkat; Viet Huong Nguyen; César Arturo Masse de La Huerta; Laetitia Rapenne; Daniel Bellet; Anne Kaminski-Cachopo; Guy Chichignoud; David Muñoz-Rojas;  Advisor: -;  Co-Author: - (2021)

    Cu2O is a promising p-type semiconductor for low-cost photovoltaics and transparent optoelectronics. However, low-cost and low-temperature fabrication of Cu2O films with good transport properties remains challenging, thus limiting their widespread adoption in devices. Here, we report Cu2O thin films of 20–80 nm thickness with hole mobility up to 92 cm2V−1s−1 using atmospheric-pressure spatial atomic layer deposition at temperatures below 260 °C, from a copper (I) hexafluoro-2,4-pentanedionate cyclooctadiene precursor. Raman spectroscopy indicates the presence of copper split vacancies and shows that the high hole mobility can be correlated to a low concentration of shallow acceptor de...