Item Infomation
Title: | Dye-labeled aromatic azides for multi-photon grafting |
Authors: | Katharina, Gallas Dominik, Wohlmuth Zhiquan, Li |
Issue Date: | 2022 |
Publisher: | Springer |
Abstract: | The synthesis of two dye-labeled azides via de-symmetrization of 2,6-bis(4-azidobenzylidene)-4-methylcyclohexanone (BAC-M) with a copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC) using fluorescent dyes is reported. An alkyne functionalized dansyl derivative and an alkyne functionalized perylene diimide derivative were used as the dyes. The photo-physical properties of these dye dyads are described, and their performance in multi-photon grafting onto polyethylene glycol-based hydrogels is investigated. While the dansyl-conjugated BAC derivate is well suited for multi-photon grafting with lasers operating at 800 nm, the perylene diimide-bearing dye does not give the desired result. |
Description: | CC BY |
URI: | https://dlib.phenikaa-uni.edu.vn/handle/PNK/8160 |
Appears in Collections | OER - Khoa học Tự nhiên |
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