Synthesis of poly(n-alkyl acrylamides) and evaluation of nanophase separation effects by temperature-dependent infrared spectroscopy

Abstract

Common linear polymers are known to undergo phase changes at the glass-transition temperature (Tg) and the melting point (Tm). In recent years, it has also been shown that molecules with long aliphatic side chains can give rise to a backbone-independent melting phenomenon, known as nanophase separation. This effect describes the self-assembly — independent of the polymer backbone — of alkyl side chains into semi-crystalline nanostructures. This work presents optimized, gram scale synthesis routes for dodecyl and octadecyl acrylamide and their respective homopolymers. Differential scanning calorimetry (DSC) experiments detected a broad endothermal signal for poly(n-dodecyl acrylamide) at − 29 °C and a narrower, more intense signal for poly(n-octadecyl acrylamide) at 34 °C. These signals indicate the nanophase separation TM of the alkyl side chains.