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DC Field | Value | Language |
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dc.contributor.author | Carola, Haslinger | - |
dc.contributor.author | Anna, Zahoranová | - |
dc.contributor.author | Stefan, Baudis | - |
dc.date.accessioned | 2023-04-20T08:58:38Z | - |
dc.date.available | 2023-04-20T08:58:38Z | - |
dc.date.issued | 2023 | - |
dc.identifier.uri | https://link.springer.com/article/10.1007/s00706-022-03013- | - |
dc.identifier.uri | https://dlib.phenikaa-uni.edu.vn/handle/PNK/8170 | - |
dc.description | CC BY | vi |
dc.description.abstract | Herein, we present a new route to synthesize poly(2-oxazoline)s (POx) with coumarin moieties as pendant groups that can be crosslinked by irradiation to form hydrogels. The synthesis of a novel coumarin-containing 2-oxazoline monomer, 2-[(4-methyl-7-coumarinyloxy)methyl]oxazoline is described in four steps and further its subsequent homo- and copolymerization with 2-ethyl-2-oxazoline (EtOx) via cationic ring-opening polymerization (CROP). The received polymers with different coumarin content (8, 4 and 2 mol%) were compared with a known copolymer synthesized via postpolymerization modification of partially hydrolyzed poly(2-ethyl-2-oxazoline) (PEtOx) with a coumarin derivative. The thermoresponsive behavior of the POx in aqueous solutions was investigated, showing a clear difference in the cloud point temperature (Tcp) between the polymers synthesized via different strategies. | vi |
dc.language.iso | en | vi |
dc.publisher | Springer | vi |
dc.subject | EtOx | vi |
dc.subject | POx) | vi |
dc.title | Synthesis of coumarin-containing poly(2-oxazoline)s and light-induced crosslinking for hydrogel formation | vi |
dc.type | Book | vi |
Appears in Collections | ||
OER - Khoa học Tự nhiên |
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