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dc.contributor.authorYuel W., Abraha-
dc.contributor.authorFrancois J. F., Jacobs-
dc.contributor.authorAlice, Brink-
dc.date.accessioned2023-04-21T01:44:29Z-
dc.date.available2023-04-21T01:44:29Z-
dc.date.issued2023-
dc.identifier.urihttps://link.springer.com/article/10.1007/s10904-023-02653-5-
dc.identifier.urihttps://dlib.phenikaa-uni.edu.vn/handle/PNK/8183-
dc.descriptionCC BYvi
dc.description.abstractDirect mixing (de novo) and Solvent Assisted Ligand Exchange (SALE) are the main methods used for the synthesis of Mixed-Linker Zeolitic Imidazolate Frameworks (ML-ZIFs). ML-ZIFs with combined –NO2 and –Br/–Cl functionalities were prepared via both synthetic routes. Thereafter the CO2 uptake of the ML-ZIFs were compared, as well as their abilities to fixate CO2 with epoxide substrates. The de novo synthesis resulted in ML-ZIFs with SOD topologies, 60: 40 (–NO2: –Br/–Cl) functionality ratios, higher porosities, better thermal stability and higher CO2 uptake than equivalent SALE products.vi
dc.language.isoenvi
dc.publisherSpringervi
dc.subjectde novovi
dc.subjectSALEvi
dc.titleEffect of Solvent Assisted Linker Exchange (SALE) and De Novo Synthetic Routes on CO2 Uptake and Fixation by Mixed-Linker Zeolitic Imidazolate Frameworksvi
dc.typeBookvi
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