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dc.contributor.authorNaunheim, Yannick-
dc.contributor.authorPerrin, Alice-
dc.contributor.authorOlive, Christian E.-
dc.date.accessioned2023-08-25T08:29:53Z-
dc.date.available2023-08-25T08:29:53Z-
dc.date.issued2023-
dc.identifier.urihttps://link.springer.com/article/10.1007/s11661-023-07152-3-
dc.identifier.urihttps://dlib.phenikaa-uni.edu.vn/handle/PNK/8960-
dc.descriptionCC-BYvi
dc.description.abstractNano-phase separating Ni–12 at. pct Ag powders are processed via high-energy ball milling and brought into a supersaturated state with a reduction of the grain size to the nanocrystalline scale, a combination that is designed to encourage rapid densification by phase separation upon heating. This unstable powder is then characterized by dilatometry, in-situ x-ray diffraction, thermogravimetry and microstructure analysis for sintering cycles up to 940 °C. However, these powder compacts exhibit excessive pore evolution and significant macroscopic swelling caused by removal of the organic process additives. This competition of organic removal with densification is known in nanocrystalline metals, but the present study adds an additional dimension of phase separation, which shifts the dominant swelling mechanism as the formation of the second phase traps the volatilizing organics and hinders the debinding process.vi
dc.language.isoenvi
dc.publisherSpringervi
dc.subjectNano-Phase Separation Interferesvi
dc.titleA Limit to Accelerated Free-Sintering: Nano-Phase Separation Interferes With Organic Debindingvi
dc.typeBookvi
Appears in CollectionsOER - Khoa học Vật liệu, Ứng dụng

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