Temperature and frequency dependent dielectric capacitance and polarization performances of low dimensional perovskite based manganese stannate

Abstract

Manganese stannate perovskite nanoparticles were synthesized by applying a complexation mediated approach. Rietveld refinement of the XRD data exhibited orthorhombic structure with space group of Pnma. The structure included eightfold coordinated Mn2+ cation, surrounded by eight O2− anions and formed MnO8 polyhedra unit. Each polyhedra unit interconnected through the corner-sharing SnO6 octahedra with the formation of a cage-like network. The temperature and frequency dependent dielectric performances of manganese stannate were measured in the form of a device, which exhibited maximum dielectric constant value ~ 3445. The high dielectric constant value was originated due to the contribution of space charge polarization and orientation polarization of dipoles within the measured frequency ranges.