Browsing by Author N.Tu
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ZnS has great potential as a valuable material for nanoscale devices because of its rich morphologies and unique structure. Although much effort has been made, the growth of high-quality ZnS crystal is still a challenge. In this paper, high-quality optically defect-free 1D ZnS nanostructures, including nanorods, nanowires, and nanobelts, were successfully synthesized on a large scale by a modified thermal evaporation method. XRD patterns and HRTEM images indicated that the ZnS nanostructures are single phases with hexagonal structures. Under optical excitation, all the ZnS nanostructures show intense UV emissions and almost no defect emissions at room temperature. Sharp UV lasing-like... |
Heterostructure alloys with controlled structure and composition are essential for future electronics and optoelectronics. While heterostructure formation creates sharp electronic junction, alloying allows bandgap tunability. Herein, ZnS/ZnO heterostructure-alloy hexagonal micropyramids are grown on Si/SiO2 wafers for the first time by facile thermal evaporation of ZnS powder. It is found that the pyramids with a based size of few micrometers are grown along different crystallographic directions and neighbored by ZnS microrods. XRD and XPS spectra showed that ZnS, ZnO, and ZnSO wurtzite phases coexist in the as-received samples |
